Is Enantiomer Assignment Possible by NMR Spectroscopy Using Residual Dipolar Couplings from Chiral Nonracemic Alignment Media?—A Critical Assessment
Identifieur interne : 000533 ( France/Analysis ); précédent : 000532; suivant : 000534Is Enantiomer Assignment Possible by NMR Spectroscopy Using Residual Dipolar Couplings from Chiral Nonracemic Alignment Media?—A Critical Assessment
Auteurs : Robert Berger [Allemagne] ; Jacques Courtieu [France] ; Roberto R. Gil [États-Unis] ; Christian Griesinger [Allemagne] ; Matthias Köck [Allemagne] ; Philippe Lesot [France] ; Burkhard Luy [Allemagne] ; Denis Merlet [France] ; Armando Navarro-Vázquez ; Michael Reggelin [Allemagne] ; Uwe M. Reinscheid [Allemagne] ; Christina M. Thiele [Allemagne] ; Markus Zweckstetter [Allemagne]Source :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2012-08-13.
English descriptors
- KwdEn :
- Absolute configuration, Alignment, Alignment tensor, Chem, Chiral, Chiral nonracemic alignment, Chiral nonracemic alignment media, Chiral nonracemic alignment medium, Conformation, Dexp, Different sets, Enantiomer, Experimental rdcs, Flexible molecules, Nonracemic, Rdcs, Residual dipolar couplings, Rigid molecule, Rigid molecules, Verlag gmbh.
- Teeft :
- Absolute configuration, Alignment, Alignment tensor, Chem, Chiral, Chiral nonracemic alignment, Chiral nonracemic alignment media, Chiral nonracemic alignment medium, Conformation, Dexp, Different sets, Enantiomer, Experimental rdcs, Flexible molecules, Nonracemic, Rdcs, Residual dipolar couplings, Rigid molecule, Rigid molecules, Verlag gmbh.
Abstract
Insensitive towards inversion: Can residual dipolar couplings (RDCs) and other anisotropic NMR observables be used to determine absolute configuration? A critical assessment of recent approaches is provided to determine the absolute configuration from RDCs.
Url:
DOI: 10.1002/anie.201107626
Affiliations:
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<front><div type="abstract">Insensitive towards inversion: Can residual dipolar couplings (RDCs) and other anisotropic NMR observables be used to determine absolute configuration? A critical assessment of recent approaches is provided to determine the absolute configuration from RDCs.</div>
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